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引用本文:高 青,齐学斌,赵志娟,等.小麦秸秆和小麦秸秆生物质炭对低质量浓度Cd2+的吸附特性研究[J].灌溉排水学报,2017,36(2):.
GAO Qing,QI Xuebin,ZHAO Zhijuan,et al.小麦秸秆和小麦秸秆生物质炭对低质量浓度Cd2+的吸附特性研究[J].灌溉排水学报,2017,36(2):.
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小麦秸秆和小麦秸秆生物质炭对低质量浓度Cd2+的吸附特性研究
高 青, 齐学斌, 赵志娟, 李中阳, 樊 涛
中国农业科学院 农田灌溉研究所, 河南 新乡 453002;.中国农业科学院 河南新乡农业水土环境野外科学观测试验站, 河南 新乡 453002;中国农业科学院 农业水资源高效安全利用重点开放实验室, 河南 新乡 453002
摘要:
针对再生水灌溉镉污染问题,研发新型低成本高效重金属吸附材料。以农业废弃小麦秸秆和小麦秸秆生物质炭为研究对象,研究了麦秆和小麦秸秆生物质炭对低质量浓度Cd2+的吸附性能及影响因素。结果表明,麦秆和小麦秸秆生物质炭对Cd2+的吸附特性符合Langmuir方程,且吸附作用主要发生在吸附开始的10 min,试验条件下,生物质炭对Cd2+去除率达90%以上,麦秆对Cd2+去除率为70%左右;pH值对麦秆吸附Cd2+影响显著,对生物质炭吸附Cd2+影响极显著,pH值为3~6时生物质炭对Cd2+的吸附效果较好。温度显著影响麦秆对Cd2+的吸附,温度对生物质炭吸附Cd2+无显著影响,当吸附材料投加量大于0.5 g/L即固液比大于0.45 g/mg时,增大二者投加量对其吸附Cd2+没有显著影响。
关键词:  小麦秸秆; 生物质炭; 吸附; Cd2+
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Absorption of Cd2+ at Low Concentration by Wheat Straw and Wheat Straw Derived-biochar
GAO Qing, QI Xuebin, ZHAO Zhijuan, LI Zhongyang, FAN Tao
Farmland Irrigation Research Institute of CAAS, Xinxiang 453002, China; Agriculture Water and Soil Environmental Field Science Station of Xinxiang City He’nan Province of CAAS, Xinxiang 453002, China; Key Laboratory of High-efficient and Safe Utilization of Agriculture Water Resource of CAAS, Xinxiang 453002, China
Abstract:
Wheat straw and wheat straw derived-biochar were taken as the research object. Adsorption property and its influential factors of Cd2+ at low concentration to the wheat straw and wheat straw derived-biochar in aqueous solution were investigated. The results indicated that adsorption isotherm fit well with Langmiur equation, adsorption equilibrium of Cd2+on wheat straw and wheat straw derived-biochar almost reached in 10 minutes. Under the experimental condition, the removal rate of Cd2+ on biochar was over 90%, which was 70% on wheat straw. There was significant effect of pH values on adsorption of Cd2+ by the biochar and wheat straw, temperature had effects on adsorption of Cd2+ by wheat straw, but there was no significant effect of temperature on adsorption of Cd2+ by the biochar. When 0.5 g/L wheat straw or biochar were used, there was no effect of different dosing quantity on adsorption of Cd2+ by wheat straw and its derived-biochar.
Key words:  wheat straw; absorption; biochar; Cd2+